4-Nitrotoluene CAS:99-99-0

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Product Name:4-Nitrotoluene
Synonyms:nci9579;NCI-C60537;nitrotoluenos;para-nitrotoluol;p-Methylnitrobenzene;p-nitro-toluen;PNT;Toluene, p-nitro-
Product Categories:4-Methylnitrobenzene;Organics;Analytical Chemistry;Environmental Endocrine Disruptors;Estradiol, etc. (Environmental Endocrine Disruptors);Solid WasteMethod Specific;2000/60/ECMore...Close...;8000 Series Solidwaste Methods;Analytical Standards;AromaticsEnvironmental Standards;Chemical Class;Environmental Standards;European Community: ISO and DIN;ExplosivesEPA;Method 8330Alphabetic;N;NA - NIAnalytical Standards;Nitro CompoundsChromatography;Volatiles/ Semivolatiles
Mol File:99-99-0.mol
4-Nitrotoluene Structure

4-Nitrotoluene Chemical Properties
Melting point 52-54 °C(lit.)
Boiling point 238 °C(lit.)
density 1.392 g/mL at 25 °C(lit.)
vapor density 4.7 (vs air)
vapor pressure 5 mm Hg ( 85 °C)
refractive index 1.5382
Fp 223 °F
storage temp. 0-6°C
solubility 0.26g/l
form Crystalline Solid
pka11.27 (Perrin, 1972)
color Yellow
Specific Gravity1.392
explosive limit1.6%(V)
Water Solubility 0.35 g/L (20 ºC)
Merck 14,6650
BRN 1906911
Henry's Law Constant5.64 at 25 °C (thermodynamic method-GC/UV spectrophotometry, Altschuh et al., 1999)
Exposure limitsNIOSH REL: TWA 2 ppm (11 mg/m3), IDLH 200 ppm; OSHA PEL: TWA 5 ppm (30 mg/m3); ACGIH TLV: TWA 2 ppm (adopted).
Stability:Stability May be shock sensitive. Incompatible with sulfuric acid, strong bases, reducing agents, strong oxidizing agents.
CAS DataBase Reference99-99-0(CAS DataBase Reference)
IARC3 (Vol. 65) 1996
NIST Chemistry ReferenceBenzene, 1-methyl-4-nitro-(99-99-0)
EPA Substance Registry Systemp-Nitrotoluene (99-99-0)

Safety Information
Hazard Codes T,N,F,Xn
Risk Statements 23/24/25-33-51/53-36/37/38-11-36-20/21/22
Safety Statements 28-37-45-61-28A-27-16-36/37-26
RIDADR UN 3446 6.1/PG 2
WGK Germany 2
RTECS XT3325000
Autoignition Temperature734 °F
HazardClass 6.1
PackingGroup II
HS Code 29042000
Hazardous Substances Data99-99-0(Hazardous Substances Data)
ToxicityLD50 orally in Rabbit: 1960 mg/kg LD50 dermal Rat > 16000 mg/kg



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